Trends in the periodic table- Electronegativity

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An explanation of electronegativity in terms of the periodic table
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Note by mia.rigby, updated more than 1 year ago More Less
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Created by eoin.examtime almost 11 years ago
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Electronegativity is defined as the relative attraction of an atom for shared pairs of electrons in a covalent bond. An atom's electronegativity is affected by both its atomic number and the distance that its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it.

Electronegativity in terms of the periodic table decreases going down a group. This is due to an increase in the atomic radius as the outermost electron is becoming further away from the attractive force of the nucleus. There is a smaller attraction between nucleus and the shared pair of electrons

As well as this, the screening effect cancels out the assumed effect of the increase in nuclear charge meaning that attraction of the nucleus for the outer electrons decreases.

Electronegativity increases across a period due to an increase in nuclear charge and a decrease in atomic radius as the attraction of the nucleus increases towards the electrons as they are pulled closer to it

Some general guidelines are: Metals are generally low in terms of electronegativity and non-metals have high values in comparison. Fluorine is more elcertonegative than oxygen, nitrogen and chlorine 

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