Atomic Structure

Description

Chemistry (Atomic Structure) Flashcards on Atomic Structure, created by Beth Ritchie on 13/11/2013.
Beth Ritchie
Flashcards by Beth Ritchie, updated more than 1 year ago
Beth Ritchie
Created by Beth Ritchie about 11 years ago
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Resource summary

Question Answer
Which 4 factors affect ionisation energy? Nuclear charge, shielding, atomic radius, repulsion due to spin
How does Nuclear Charge affect ionisation energy? If there are more protons, ionisation energy will be increased due to greater pull on electrons.
How does shielding affect ionisation energy? The more shielding, the more repulsion and thus the lower ionisation energy.
How does atomic radius affect ionisation energy? Larger atomic radius means lower ionisation energy, as they feel the electrostatic force less strongly.
How does repulsion due to spin affect ionisation energy? If the outer electron is paired in a partially filled shell, it is unstable and will be repelled by the other electron in it's pair due to opposite spins. In this case, ionisation energy will decrease.
What is ionisation energy? The energy required to remove an outer electron.
How does ionisation energy change across the period? Ionisation energy increases due to increasing nuclear charge. There will be drops (ie. P - S) where shells are partially filled.
How does ionisation energy change going down the group? Ionisation energy decreases due to greater atomic radius and more shielding.
What are the 6 stages in the mass spectrometer? Vaporisation, ionisation, acceleration, deflection, detection and recording.
What is the definition of isotope? Atoms of an element with a different number of neutrons. They are chemically identical.
Define atomic number. Proton number, Z. The number of protons that one atom of an element contains, and therefore the number of electrons it has.
Define Mass number. A. The number of protons and neutrons an atom of an element contains.
Define atom. The smallest component of an element showing the chemical properties of that element.
Define relative atomic mass. The average mass of an atom relative to 1/12th the mass of a C12 atom.
Define relative molecular mass. The average mass of a molecule relative to 1/12th the mass of a C12 atom.
Define relative isotopic mass. The average mass of an isotope relative to 1/12th the mass of a C12 atom.
What is first ionisation energy? The minimum energy required to remove an ourter electron from one mole of gaseous atoms to form gaseous 1+ atoms.
What is second ionisation energy? The minimum energy required to remove an outer electron from one mole of gaseous 1+ ions to form gaseous 2+ ions.
What is the Aufbau principle? Electrons fill orbitals in order of increasing energy.
What are the four orbitals? S, P, D and F
What is an S sublevel like? It is spherical and can hold 2 electrons.
What is a P orbital like? It holds 6 electrons and is comprised of 3 dumbbells which each hold 2 electrons.
What is hunts rule? Electrons have a property called spin, and they spin in one of two directions. They will always arrange themselves so the number of opposite spins is minimised.
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