Halogenoalkanes Equations

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AS level Chemistry (Unit 2: Organic) Flashcards on Halogenoalkanes Equations, created by maevedevlin on 02/03/2014.
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Flashcards by maevedevlin, updated more than 1 year ago
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Created by maevedevlin over 10 years ago
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Question Answer
Producing a Halogenoalkane From an Alkane General Equation, Conditions, Type of Reaction, Mechanism GE: Alkane + Halogen → Halegenoalkane + Hydrogen Halide Conditions: UV light Type: Substitution Mechanism: Free-radical Substitution
Producing a Halogenoalkane From an Alkene General Equation, Conditions, Type of Reaction, Mechanism GE: Alkene + Hydrogen Halide → Halogenoalkane Conditions: None required Type: Addition Mechanism: Electrophillic addition
Producing a Halogenoalkane From an Alcohol General Equation, Conditions, Type of reaction GE: Alcohol + HX → Halogenoalkane + H₂O Conditions: HBr generated from NaBr + conc. H₂SO₄ in situ; heat under reflux Type: Substitution
Reaction with Alkali OHˉ General Equation, Conditions, Type of Reaction GE: Halogenoalkane + OHˉ → alcohol + Xˉ Conditions: Heat under reflux with aqueous sodium Hydroxide solution with a small quantity of ethanol for one hour Type: Substitution/ Hydrolysis Mechanism: Nucleophillic Substitution
Reaction with Ammonia NH₃ General Equation, Conditions, Type of Reaction, Mechanism GE: Halogenoalkane + NH₃ → ammine + HX (hydrogen halide) Conditions: Heated with ethanolic ammonia in a sealed tube Type: Substitution Mechanism: Nucleophillic Substitution
Reaction with Cyanide Ions, CNˉ General Equation, Conditions, Type of Reaction, Mechanism GE: Halogenoalkane + CNˉ → Nitrile + Xˉ (halide ion) Conditions: Halogenoalkane dissolved in ethanol dropped into aqueous solution of KCN or NaCN. Heated under reflux. Type: Substitution Mechanism: Nucleophillic Substitution
Reaction with Potassium Hydroxide, KOH, in Ethanol General Equation, Conditions, Type or Reaction GE: Halogenoalkane + KOH → alkene + KX + H₂O Conditions: Halogenoalkane treated with hot ethanolic potassium hydroxide solution Type: Elimination
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