topic 8 - energetics I

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GSCE Chemistry Flashcards on topic 8 - energetics I, created by Leanne Tan on 29/01/2022.
Leanne Tan
Flashcards by Leanne Tan, updated more than 1 year ago
Leanne Tan
Created by Leanne Tan almost 3 years ago
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Question Answer
define enthalpy change the amount of heat energy taken in or given out during any change in the system, provided the pressure is constant
what is an exothermic reaction? - energy is transferred from the system to the surroundings (usually releasing heat) - the overall enthalpy change is negative
what is an endothermic reaction? - when (thermal) energy is absorbed from the surroundings into the system - the overall enthalpy change is positive
define the standard enthalpy change of formation the enthalpy change when 1 mole of a compound is formed from its elements under standard temperature and pressure
what is standard pressure? 100kPa (~1 atmosphere)
what is standard temperature? 298 K, 24.85 Celcius
define the standard enthalpy change of combustion the enthalpy change when 1 mole of a substance is completely burned in oxygen under standard conditions
what is standard concentration? 1 mol/dm3
what does incomplete combustion produce? - carbon particulates - water - carbon monoxide - will be less exothermic than complete combustion
define the standard enthalpy of electron affinity the energy released when 1 mole of gaseous atoms each gains an electron to form 1 mole of gaseous 1- ions
define the standard enthalpy of neutralisation the enthalpy change when acid and alkali react together under standard conditions to form 1 mole of water
define the standard enthalpy of atomisation the heat energy needed to produce 1 mole of gaseous atoms from the element in its standard state
define the standard enthalpy change of ionisation energy the energy required to remove the most loosely held electron from 1 mole of gaseous atoms to produce 1 mole of gaseous 1+ ions
define the standard enthalpy change of lattice enthalpy the heat energy change when 1 mole of solid ionic lattice is formed from its scattered gaseous ions
are neutralisation reactions exothermic or endothermic? always exothermic
state Hess' law total enthalpy change for a reaction is independent of the route taken to get from reactants to products
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